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Empirical evidence increasingly suggests that teacher leadership has a significant impact on both student learning and school improvement. This study tested a mediation model of the processes linking teacher leadership and instructional quality in China, in which teacher responsibility and teacher collaboration acting as mediators. A structural equation modeling analysis was conducted on data collected from 641 teachers in S province, China. The results revealed significant direct and indirect effects of teacher leadership on instructional quality, mediated by teacher responsibility and teacher collaboration. The two mediating variables also played a role in chain mediation. Implications for understanding the influence of teacher leadership and improving instructional quality are discussed.