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This study aims to uncover whether AI self-efficacy (self-efficacy in AI technological, pedagogical, and content knowledge) mediates or moderates the relationship between facilitating conditions and intention to teach with AI. A total of 765 English teachers were recruited from mainland China. The current study demonstrated that facilitating conditions positively predicted self-efficacy, which in turn positively predicted intention to teach with AI. The interaction produced a nonsignificant relation to intention to teach with AI. We concluded that self-efficacy mediated but did not moderate the relationship between facilitating conditions and intention to teach with AI. Our findings underscore the imperative of cultivating teachers’ self-efficacy, particularly in pedagogical and content knowledge.