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This paper examines the limitations of the Marginal Maximum Likelihood with Expectation-Maximization (MML-EM) algorithm for estimating 2PLM parameters in Item Response Theory (IRT), especially with limited samples and mismatched abilities and difficulties. We propose a deep learning model based on Dynamic Key-Value Memory Networks (DKVMN) and Deep-IRT, incorporating separate networks for examinees and items. Versus MML-EM, the model yields better RMSE and Pearson correlations under constrained conditions, showing promise as a cold-start estimator.