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To improve science performance, we examined how internet use for schoolwork and ICT self-efficacy influence outcomes among English Language Learners (ELLs). Using structural equation modeling, we explored both direct and indirect pathways from internet use to science achievement, mediated by ICT- and science self-efficacy. Findings revealed that internet use had significant positive effects on science performance, both directly and indirectly through self-efficacy constructs. ICT self-efficacy also showed strong direct and indirect associations via science self-efficacy. These results support the importance of fostering digital skills and confidence, especially among at-risk groups like ELL students. We discuss implications for addressing digital equity in the (post-)pandemic era, where disparities in access and support remain a major concern.