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Creative thinking is a key trait of innovative talents, yet empirical evidence on how Information and Communication Technology (ICT) affects its development remains limited. This study investigates the relationship between students’ ICT use and creative thinking using PISA 2022 data (N=181,504 students). Multilevel linear modeling revealed an inverted-U relationship, where moderate ICT use (both study and entertainment) enhanced creative thinking, while excessive use diminished it. Family ESCS and school digital resources significantly strengthening this curvilinear effect. Creative self-efficacy partially mediated the positive effect of moderate use but acted as a suppressor under excessive use. Findings highlight the need for optimized ICT use, equitable digital resource allocation, and fostering positive psychological experiences to maximize technology's potential for nurturing creative thinking.