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This paper investigates effects of social media on collective action participation by addressing selection bias, disentangling social media mechanisms, and analyzing mediating socio-psychological factors. Utilizing a unique designed survey that allows for addressing selection bias and endogeneity control, I investigate a large scale street demonstration in Taiwan. I propose a structural-cognitive model that synthesizes macro level technological factors and individual level incentives to explain determinants of collective action participation. I find that social media expression, rather than social media information, has direct effects on protest participation. Furthermore, the effect is unlikely due to selection bias, which is a large limitation of current studies. Regarding the macro-micro model, social media expression increases levels of identification, friend positive incentive, and individual efficacy, which in turn lead to protest participation. My results suggest social media as a new mobilization structure that changes psychological states of individuals, which broadens the pool of collective action sympathizers. To my knowledge, this paper is the first to propose such a macro-micro model to explain mechanisms of social media on collective action. The study demonstrates how a synthetic framework between disciplines of sociology, psychology, and communication enables a holistic understanding of collective action.