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The literature has discussed the involvement of Mafia groups and organized groups of entrepreneurs in waste crimes. However, a comparative analysis of the modi operandi of both criminal groups and potential connections between them has been seldom undertaken. This research seeks to address this gap by conducting an analysis of judicial cases to comprehend the motivations and methods employed by both types of criminal organizations. The study delves into the strategies utilized to trafficking waste, infiltrate the waste industry, the profiles of external actors colluding with criminal networks, and the techniques employed for money laundering. Preliminary findings suggest that Mafia groups are primarily involved in national-level illegal waste management, whereas organized groups of entrepreneurs engage also in transnational crimes. Mafia groups leverage territorial control and political connections, adopting illegal operational patterns from various industries. Conversely, criminal networks of entrepreneurs, while lacking intimidation power, exhibit flexibility and international connectivity, particularly in engaging in waste trafficking. By shedding light on these dynamics, this research contributes to a better understanding of the complexities surrounding waste crimes and the interplay between different criminal entities.