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Large language models (LLMs) are increasingly embedded in daily life, raising a question: how do people interact with artificial intelligence (AI), and does it resemble human–human talk? Using 148,484 human-AI conversations from mainland China and Hong Kong, we track alignment from conversation-level convergence to message-level accommodation and symmetry from linguistic and semantic perspectives. We find pervasive semantic convergence (~77%) but frequent linguistic divergence (~57%); accommodation is asymmetric and AI-led. Convergence is shaped by topic tightness, conversational context (language and location), conversation style (longer sentences, emoji), psychological motivations (achievement, tentativeness), and social focus (affiliation/friends), revealing AI-divide patterns.